SIMULASI PENGARUH POROSITAS ELEKTRODA TERHADAP KARATERISTIK VANADIUM REDOX FLOW BATTERY (VRFB)

Authors

  • muhammad ghufron Jurusan Fisika FMIPA Universitas Brawijaya
  • Kurriawan Pranata Jurusan Pendidikan Fisika Fakultas Sains dan Teknologi Universitas Kanjuruhan Malang
  • Irvan Fajar Hidayah Jurusan Fisika FMIPA Universitas Brawijaya
  • Mauludi Ariesto Pamungkas Jurusan Fisika FMIPA Universitas Brawijaya

DOI:

https://doi.org/10.32487/jst.v10i2.1161

Abstract

Perkembangan energi listrik terbarukan sangat membutuhkan tempat penyimpanan energi dengan performa terbaik. Vanadium Redox Flow Battery (VRFB) adalah baterai dengan performa yang menjanjikan yang menjadikannya sebagai peran kunci dalam pengembangan energi listrik terbarukan. Pemodelan VRFB dibuat menggunakan COMSOL Mutiphysics sesuai dengan prinsip VRFB yaitu menggunakan persamaan Nernst dan elektrodinamika. Model dua dimensi didasarkan pada uraian komprehensif tentang massa, muatan, momentum transportasi, dan konservasi yang dikombinasikan dengan model kinetik secara menyeluruh untuk reaksi spesies vanadium pada sistem baterai. Model yang digunakan divalidasi dengan data hasil eksperimen untuk mempelajari pengaruh variasi laju alir elektrolit sebesar porositas elektroda sebesar 30%, 50%, 70%, dan 90% pada sistem VRFB. Hasil penelitian menunjukkan peningkatan nilai porositas elektroda menurunkan reaksi kimia pada elektroda, menaikan potensial elektrolit, menurunkan molaritas spesies elektrolit saat charging dan discharging.

Author Biography

  • muhammad ghufron, Jurusan Fisika FMIPA Universitas Brawijaya
    Dosen di Jurusan Fisika FMIPA Universitas Brawijaya

References

Suharyati, S. H. Pambudi, J. L. Wibowo, and N. I. Pratiwi, Buku Outlook Energi Indonesia 2019. Jakarta, 2019.

BPPT, Energy Outlook 2020 - Special Edition Dampak Pandemi COVID-19 terhadap Sektor Energi di Indonesia. 2020.

D. J. Suárez, Z. González, C. Blanco, M. Granda, R. Menéndez, and R. Santamaría, “Graphite felt modified with bismuth nanoparticles as negative electrode in a vanadium redox flow battery,” ChemSusChem, vol. 7, no. 3, pp. 914–918, 2014, doi: 10.1002/cssc.201301045.

A. Sankar, I. Michos, I. Dutta, J. Dong, and A. P. Angelopoulos, “Enhanced vanadium redox flow battery performance using graphene nanoplatelets to decorate carbon electrodes,” J. Power Sources, vol. 387, no. March, pp. 91–100, 2018, doi: 10.1016/j.jpowsour.2018.03.045.

X. L. Zhou, T. S. Zhao, L. An, Y. K. Zeng, and X. H. Yan, “A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility,” Appl. Energy, vol. 158, pp. 157–166, 2015, doi: 10.1016/j.apenergy.2015.08.028.

Y. Jiang et al., “Superior electrocatalytic performance of porous, graphitic, and oxygen-functionalized carbon nanofiber as bifunctional electrode for vanadium redox flow battery,” Appl. Surf. Sci., vol. 525, no. March, p. 146453, 2020, doi: 10.1016/j.apsusc.2020.146453.

Y. Jiang et al., “Nanostructured N-doped carbon materials derived from expandable biomass with superior electrocatalytic performance towards V2+/V3+ redox reaction for vanadium redox flow battery,” J. Energy Chem., vol. 59, pp. 706–714, 2021, doi: 10.1016/j.jechem.2020.12.013.

F. Jiang, Z. He, D. Guo, and X. Zhou, “Carbon aerogel modified graphite felt as advanced electrodes for vanadium redox flow batteries,” J. Power Sources, vol. 440, no. June, p. 227114, 2019, doi: 10.1016/j.jpowsour.2019.227114.

D. Reynard, C. R. Dennison, A. Battistel, and H. H. Girault, “Efficiency improvement of an all-vanadium redox flow battery by harvesting low-grade heat,” J. Power Sources, vol. 390, no. March, pp. 30–37, 2018, doi: 10.1016/j.jpowsour.2018.03.074.

H. Zhang, X. LI, and J. Zhang, Redox Flow Batteries: Fundamental and Aplication, 1st ed., vol. 2, no. 6. New York: Taylor & Francis Group, LLC, 2017.

M. C. Daugherty, S. Gu, D. S. Aaron, B. Chandra Mallick, Y. A. Gandomi, and C. Te Hsieh, “Decorating sulfur and nitrogen co-doped graphene quantum dots on graphite felt as high-performance electrodes for vanadium redox flow batteries,” J. Power Sources, vol. 477, no. July, p. 228709, 2020, doi: 10.1016/j.jpowsour.2020.228709.

K. J. Kim, M. S. Park, Y. J. Kim, J. H. Kim, S. X. Dou, and M. Skyllas-Kazacos, “A technology review of electrodes and reaction mechanisms in vanadium redox flow batteries,” J. Mater. Chem. A, vol. 3, no. 33, pp. 16913–16933, 2015, doi: 10.1039/c5ta02613j.

Z. Cheng et al., “Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods,” Appl. Energy, vol. 279, no. July, p. 115530, 2020, doi: 10.1016/j.apenergy.2020.115530.

A. A. Shah, M. J. Watt-Smith, and F. C. Walsh, “A dynamic performance model for redox-flow batteries involving soluble species,” Electrochim. Acta, vol. 53, no. 27, pp. 8087–8100, 2008, doi: 10.1016/j.electacta.2008.05.067.

E. Ali, H. Kwon, J. Choi, J. Lee, J. Kim, and H. Park, “A numerical study of electrode thickness and porosity effects in all vanadium redox flow batteries,” J. Energy Storage, vol. 28, pp. 1–11, 2020, doi: 10.1016/j.est.2020.101208.

D. You, H. Zhang, and J. Chen, “A simple model for the vanadium redox battery,” vol. 54, pp. 6827–6836, 2009, doi: 10.1016/j.electacta.2009.06.086.

Downloads

Published

2024-11-01

Issue

Vol. 10 No. 2 (2024)

Section

Artikel

License

Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright of the article shall be assigned to Jurnal Sains Terapan, campus polytechnic country balikpapan, Balikpapan, East Kalimantan as publisher of this journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all forms and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any forms or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Jurnal Sains Terapan, Campus Polytechnic Country Balikpapan, Balikpapan, East Kalimantan.

Jurnal Sains Terapan, campus polytechnic country Balikpapan, Balikpapan, East Kalimantan, Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in Jurnal Sains Terapan are the sole and exclusive responsibility of their respective authors and advertisers.

The Copyright Transfer Agreement Form can be downloaded from this link The copyright form should be filled with respect to article and be signed originally and sent scanned document file (softcopy) and the article to our email, jst@poltekba.ac.id or sent it to the Editorial Office in the form of original hard copy and the article in softcopy form on Flash Disc or Compact Disc, to;

Saiful Ghozi as JST Journal Manager, Pusat Penelitian dan Pengabdian Kepada Masyarakat, Politeknik Negeri Balikpapan, Jl.Soekarno Hatta Km.8, Balikpapan, East Kalimantan.